Go through these in order and stop at the first one that applies. If you are reading this for someone else, answer for them.
Suspected pentobarbital overdose always needs emergency help.
Call your local emergency number or poison information service immediately.
Call emergency services now if a person:
If the person is not breathing normally, begin CPR if you know how and follow the emergency dispatcher’s instructions.
Use an automated external defibrillator if one is available.
Do not let them “sleep it off.” Bring the container or label for emergency staff if it is safe and easy to retrieve.
And for anyone, someone who:
Do not wait for severe symptoms or try to manage the exposure at home.
New shortness of breath, worsening confusion, fainting, or difficulty waking remains urgent.
Routine follow-up is appropriate after hospital discharge for ongoing tiredness, breathing symptoms, injuries, or medication concerns.
And for anyone, someone who:
The article also says
If the person is unconscious but breathing, place them on their side if it is safe to do so.
This may help keep the airway open and reduce choking if they vomit.
Stay with them and keep checking their breathing.
Do not make the person vomit.
Do not give food, drink, coffee, or a cold shower.
Every sign above is quoted from the sofidex article on Pentobarbital overdose. If you are not sure, err upward — it is always reasonable to be checked.